Purification of Sugarcane Juice (Saccharum officinarum L.) Using Chitosan Membrane with Dead-End Flow System

Yusuf Hendrawan, Ayu Diyaratnasari, Sandra Malin Sutan, Muchnuria Rachmawati, Yusuf Wibisono

Abstract


The purification process of sugarcane juice in a sugar factory mostly uses sulphitation process, separating clear juice from dirty juice using a sedimentation system. Impurities on the processing of sugarcane juice will further cause difficulties, the formation of color, an increase in viscosity, and reducing sugar recovery. Membrane purification technology is offered to overcome these problems. This study aims to determine the effect of chitosan and acetic acid on the performance of chitosan membranes in the clearance of sugarcane juice and to find the best concentration of chitosan and acetic acid for the purification process of sugarcane juice. The filtration process was performed by using the chitosan membrane to process a clear sugarcane juice sample from the pretreatment result, which is assumed as clear juice product from sulphitation process in sugar factory. The results showed that (1) the result of pretreatment had the value from TSS (Total Soluble Solids) of 15.4%; turbidity of 82.33 NTU; and the ICUMSA (International Commission for Uniform Methods of Sugar Analysis) colour of 14970.02 IU. (2) After filtration using membrane, better quality of pretreatment clear sugarcane juice is obtained, characterized by increasing chitosan concentration at each acetic acid level, rejection value of TSS, turbidity, and ICUMSA colour. (3) The best treatment result based on Zeleny multiple attribute method is found in chitosan membrane with concentration of 4%, acetic acid concentration of 1.5% to inject TSS until reaching 12.64%, ICUMSA until reaching 9.89%, and rejection of turbidity until reaching 63.61%. Higher chitosan concentration caused small pore size of the membrane.

Keywords


acetic acid; chitosan; membrane; sugarcane juice purification.

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References


Fang, Y., Ellis, A., Uchimiya, M., and Strathmann, T.J. “Selective oxidation of colour-inducing constituents in raw sugar cane juice with potassium permanganate”, Food Chemistry, 298, 125036, 2019.

Lemos, S.V., Salgado Jr, A.P., Duerte, A., de Souza Jr, M.A., and Antunes, F.A. “Agroindustrial best practices that contribute to technical efficiency in Brazilian sugar and ethanol production mills”, Energy, 177, pp397-411, 2019.

Bano, I., Arshad, M., Yasin, T., Ghauri, M.A., Younus, M. “Chitosan: A potential biopolymer for wound management”, International Journal of Biological Macromolecules, 102, pp380-383, 2017.

Adam, M.R., Othman, M.H.D., Samah, R.A., Puteh, M.H., Ismail, A.F., Mustafa, A., Rahman, M.A., and Jaafar, J. “Current trends and future prospects of ammonia removal in wastewater: A comprehensive review on adsorptive membrane development”, Separation and Purification Technology, 213, pp114-132, 2019.

Ghaemi, N., Daraei, P., Akhlaghi, F.S. “Polyethersulfone nanopurification membrane embedded by chitosan nanoparticles: Fabrication, characterization and performance in nitrate removal from water”, Carbohydrate Polymers, 191, pp142-151, 2018.

Taghizadeh, M.T., Siyahi, V., Sorkhabi, H.A., and Zarrini, G. “ZnO, AgCl and AgCl/ZnO nanocomposites incorporated chitosan in the form of hydrogel beads for photocatalytic degradation of MB, E. coli and S. aureus”, International Journal of Biological Macromolecules, https://doi.org/10.1016/j.ijbiomac.2019.10.070, 2019.

Malinkina, O.N., Gegel, N.O., and Shipovskaya, A.B. “Hydrodynamic behavior of chitosan hydrochloride macromolecules in aqueous solutions of D- and l-ascorbic acid”, Journal of Molecular Liquids, 284, pp75-81, 2019.

Cheah, W.Y., Show, P.L., Ng, I.S., Lin, G.Y., and Chang, Y.K. “Antibacterial activity of quaternized chitosan modified nanofiber membrane”, International Journal of Biological Macromolecules, 126, pp569-577, 2019.

Abdolrahimi, M., Seifi, M., and Ramezanzadeh, M.H. “Study the effect of acetic acid on structural, optical and mechanical properties of PVA/chitosan/MWCNT films”, Chinese Journal of Physics, 56, pp221-230, 2018.

Cahyaningrum, S.E., Widyastuti, N., and Qomariah, N. “Purification of uric acid using ultra purification membrane chitosan-glutaraldehyde-alginate”, Research Journal of Pharmaceutical, Biological, and Chemical Sciences, 5(3), pp999-1005, 2014.

Ghani, M., Gharehaghaji, A.A., Arami, M., Takhtkuse, N., and Rezaei, B. “Fabrication of electrospun polyamide-6/chitosan nanofibrous membrane toward anionic dyes removal”, Journal of Nanotechnology, 2014, [278418]. DOI: 10.1155/2014/278418, 2014.

Rahimi, Z., Zinatizadeh, A.A., and Zinadini, S. “Preparation and characterization of a high antibiofouling ultrapurification PES membrane using OCMCS-Fe3O4 for application in MBR treating wastewater”, Journal of Applied Research in Water and Wastewater, 1, pp13-17, 2014.

Rupiasih, N.N., Purnomo, R.R., and Sumadiyasa, M. “Preparation and application of chitosan membranes to filter silver from X-ray film processing wastes”, Journal of Physics: Conference Series, 710 012009, 2016.

Prabhu, K.B., Saidutta, M.B., Isloor, A.M., and Hebbar, R. “Improvement in performance of polysulfone membranes through the incorporation of chitosan - (3 – phenyl - 1h – pyrazole – 4 - carbaldehyde)”, Chemical Engineering, 4, pp1-14, 2017.

Li, L., Zhang, J., Li, Y., and Yang, C. “Removal of Cr (VI) with a spiral wound chitosan nanofiber membrane module via dead-end filtration”, Journal of Membrane Science, 544, pp333-341, 2017.

Khoerunnisa, F., Rahmah, W., Ooi, B.S., Dwihermiati, E., Nashrah, N., Fatimah, S., Ko, Y.G., and Ng, E.P. “Chitosan/PEG/MWCNT/Iodine composite membrane with enhanced antibacterial properties for dye wastewater treatment”, Journal of Environmental Chemical Engineering, 8(2), 103686, 2020.

Kolenyk, I., Konovalova, V., Kharchenko, K., Burban, A., Kujawa, J., and Kujawski, W. “Enhanced transport and antifouling properties of polyethersulfone membranes modified with α-amylase incorporated in chitosan-based polymeric micelles”, Journal of Membrane Science, 595, 117605, 2020.

Luo, J., Hang, X., Zhai, W., Qi, B., Song, W., Chen, X., and Wan, Y. “Refining sugarcane juice by an integrated membrane process: Purification behavior of polymeric membrane at high temperature”, Journal of Membrane Science, 509, pp105-115, 2016.

Bhattacharjee, C., Saxena, V.K., and Dutta, S. “Fruit juice processing using membrane technology: A review”, Innovative Food Science & Technologies, 43, pp136-153, 2017.

Conidi, C., Drioli, E., and Cassano, A. “Membrane-based agro-food production processes for polyphenol separation, purification and concentration”, Current Opinion in Food Science, 23, pp149-164, 2018.

Pal, P., Pandey, J.P., and Sen, G. “Grafted sesbania gum: A novel derivative for sugarcane juice clarification”, International Journal of Biological Macromolecules, 114, pp349-356, 2018.

Urosevic, T., Povrenovic, D., Vulkasavljevic, P., Urosevic, I., and Stevanovic, S. “Recent developments in microfiltration and ultrafiltration of fruit juices”, Food and Bioproducts processing, 106, pp147-161, 2017.

Servi, A.T., Burrieza, E.G., Warsinger, D.M., Livernois, W., Notarangelo, K., Kharaz, J., Lienhard, J.H.V., Arafat, H.A., and Gleason, K.K. “The effects of iCVD film thickness and conformality on the permeability and wetting of MD membranes”, Journal of Membrane Science, 523, pp470-479, 2017.

He, M., Zhang, S., Su, Y., Zhang, R., Liu, Y., and Jiang, Z. “Manipulating membrane surface porosity and pore size by in-situ assembly of Pluronic F127 and tannin”, Journal of Membrane Science, 556, pp285-292, 2018.

Swaminathan, J., Chung, H.W., Warsinger, D.M., and Lienhard, J.H. “Energy efficiency of membrane distillation up to high salinity: Evaluating critical system size and optimal membrane thickness”, Applied Energy, 211, pp715-734, 2018.

Madsen, H.T., Nissen, S.S., Muff, J., and Sogard, E.G. “Pressure retarded osmosis from hyperjuice solutions: Investigating commercial FO membranes at high pressures”, Desalination, 420, pp183-190, 2017.

Huang, T., Chen, J.L., Zhing, T., and Liu, P. “Improving permeability and antifouling performance of poly (ether ether ketone) membranes by photo-induced graft polymerization”, Materials Today Communications, 23, 100945, 2020.

Wang, L., Liu, H., Zhang, W., Yu, T., Jin, Q, Fu, B., and Liu, H. “Recovery of organic matters in wastewater by self-forming dynamic membrane bioreactor: Performance and membrane fouling”, Chemosphere, 203, pp123-131, 2018.

Liu, Y., Su, Y., Cao, J., Guan, J., Zhang, R., He, M., Fan, L., Zhang, Q., and Jiang, Z. “Antifouling, high-flux oil/water separation carbon nanotube membranes by polymer-mediated surface charging and hydrophilization”, Journal of Membrane Science, 542, pp254-263, 2017.

Qian, X., Li, N., Wang, Q., and Ji, S. “Chitosan/graphene oxide mixed matrix membrane with enhanced water permeability for high-salinity water desalination by pervaporation”, Desalination, 438, pp83-96, 2018.

Elizalde, C.N., Al-Gharabli, S., Kujawa, J., Mavukkandy, M., Hasan, S.W., and Arafat, H.A. “Fabrication of blend polyvinylidene fluoride/chitosan membranes for enhanced flux and fouling resistance”, Separation and Purification Technology, 190, pp68-76, 2018.

Bakhshayesh, B.E., Imhoff, P.T., and Dentel, S.K. “Assessing clogging of laminated hydrophobic membrane during fecal sludge drying”, Science of The Total Environment, 627, pp713-722, 2018.

Melo, N.F.C.B., Soares, B.L.M., Diniz, K.M., Leal, C.F., Canto, D., Flores, M.A.P., Filho, J.H.C.T., Galembeck, A., Stamford, T.L.M., Arnaud, T.M.S., and Stamford, T.C.M. “Effects of fungal chitosan nanoparticles as eco-friendly edible coatings on the quality of postharvest table grapes”, Postharvest Biology and Technology, 139, pp56-66, 2018.

Dudek, G., Turczyn, R., and Konieczny, K. “Robust poly(vinyl alcohol) membranes containing chitosan/chitosan derivatives microparticles for pervaporative dehydration of ethanol”, Separation and Purification Technology, 234, 116094, 2020.

Shen, Y. and Yang, H. “Effect of preharvest chitosan-g-salicylic acid treatment on postharvest table grape quality, shelf life, and resistance to Botrytis cinerea-induced spoilage”, Scientia Horticulturae, 224, pp367-373, 2017.

Jane, J., Shen, L., Wang, L., and Maningat, C. “Preparation and Properties of Small – Particle Corn Starch”, Journal of Cereal Chemical, 69(3), pp280-283, 1992.

Kaszuba, M., McKnight, D., Connah, M., and Watson, F. “Measuring Sub Nanometre Sizes Using Dynamic Light Scattering”, Journal of Nanoparticle, 10, pp823-829, 2007.

Erickson, H. “Size and Shape of Protein Molecules at The Nanometer Level Determined by Sedimentation, Gel Filtration, and Electron Microscopy”, Journal of Biological Procedures, 11(1), pp32-52, 2009.

Soumya, R., Ghosh, S., and Abraham, E. “Preparation and Characterization of Guar Gum Nanoparticles”, International Journal of Biological Macromolecules, 46(2), pp267-269, 2010.

Vainio, U., Maximova, N., Hortling, B., Laine, J., Stenius, P., Simola, L., Gravitis, J., and Serimaa, R. “Morphology of Dry Lignins and Size and Shape of Dissolved Kraft Lignin Particles by X-Ray Scattering”, Journal of Langmuir, 20(22), pp9736–9744, 2004.

Nystorm, M., Kaipia, L., and Luque, S. “Fouling and retention of nanopurification membranes”, Journal of Membrane Science, 98(3), pp249-262, 1995.

Nataraj, S.K., Hosamani, K.M., and Aminabhavi, T.M. “Nanopurification and reverse osmosis thin film composite membrane module for the removal of dye and salts from the simulated mixtures”, Desalination, 249(1), pp12-17, 2009.

Ghosal, S., Ebert, J., and Self, S. Chemical Composition and Size Distributions for Fly Ashes, Department of Mechanical Engineering, Stanford University, California, 2018.

Agbovi, H.K. and Wilson, L.D. “Design of amphoteric chitosan flocculants for phosphate and turbidity removal in wastewater”, Carbohydrate Polymers, 189, pp360-370, 2018.

Zhang, Z., Jing, R., Qian, J., Zhang, K., Ma, G., Chang, X., Zhang, M., and Li, Y. “Coagulation of low temperature and low turbidity water: Adjusting basicity of polyaluminum chloride (PAC) and using chitosan as coagulant aid”, Separation and Purification Technology, 206, pp131-139, 2018.

Gullett, B., Blom, J., and Cunningham, R. “Porosity, Surface Area, and Particle Size Effects of CaO Reacting With SO2 at 1100oC”, Journal Reactivity of Solids, 6(2-3), pp263-275, 2001.

Li, X., Zhou, M., Jia, J., and Jia, Q. “A water-insoluble viologen-based β-cyclodextrin polymer for selective adsorption toward anionic dyes”, Reactive and Functional Polymers, 126, pp20-26, 2018.

Thakkar, R., Thakkar, R., Pillai, A., Ashour, E.A., and Repka, M.A. “Systematic screening of pharmaceutical polymers for hot melt extrusion processing: a comprehensive review”, International Journal of Pharmaceutics, 576, 118989, 2020.

Wu, D., and Ji, Y. “Influence of polymeric excipients on the solubility of aspirin: Experimental measurement and model prediction”, Fluid Phase Equilibria, 508, 112450, 2020.

Bouchard, D.M., Benoit, S., Doyen, A., Britten, M., and Pouliot, Y. “Process efficiency of casein separation from milk using polymeric spiral-wound micropurification membranes”, Journal of Dairy Science, 100(11), pp8838-8848, 2017.




DOI: http://dx.doi.org/10.18517/ijaseit.10.6.6087

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