Kinetic Study of Pyrolysis of Ulin Wood Residue using Thermogravimetric Analysis

Aitia Mulyawati Widiyannita, Yano Surya Pradana, Rochim Bakti Cahyono, - Sutijan, Tomohiro Akiyama, Arief Budiman

Abstract


Biomass as a renewable and sustainable energy source is expected to solve the energy crisis problem. Ulin wood residues as a biomass source could be converted into bioenergy utilizing the pyrolysis process since its primary component is a hydrocarbon. Pyrolysis process has received many interests for bioenergy production from biomass, elevating the importance of the kinetic study of pyrolysis. The kinetic study of pyrolysis is related to the beginning stage behavior of gasification and combustion process. The kinetic mechanism of pyrolysis is analyzed using Thermogravimetry Analysis (TGA), by estimating the mass decomposition at solid-state that shows TG and DTG curve. The TG and DTG curves were analyzed to see the effect of heating rate on decomposition temperature. This experiment was performed by heating 10 mg of Ulin wood sawdust from ambient temperature to 1473 K utilizing 100 mL/min of nitrogen (N2) gas as carrier gas at various heating rate: 5, 10, 20, and 50 K/min. The kinetic parameters were determined by applying the iso-conversional methods, the Kissinger-Akahira-Sunose (KAS) and Flynn-Wall-Ozawa (FWO) methods, and then compared the results with the non iso-conversional method, using Kissinger method. The average value of activation energy calculated using the KAS and FWO methods are 253.5514 and 245.2512 kJ/mol, with the average value of constant coefficient square (R2) of 0.9848 and 0.9859, respectively, whereas the calculated activation energy and R2 using the Kissinger method are 237.4478 kJ/mol and 0.8520, respectively.

Keywords


ulin wood residues; pyrolysis; thermogravimetric analysis; iso-conversional method; kinetic parameters.

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References


I. B. P. Mahardika, W. Trisunaryanti, T. Triyono, D. P. Wijaya, & K. Dewi, “Transesterification of used cooking oil using CaO/MCM-41 catalyst synthesized from lapindo mud by sonochemical method,†Indones. J. Chem., 17, (3), pp. 509–515, Nov. 2017, doi: 10.22146/ijc.26561.

S. Jamilatun et al., “Ex-situ catalytic upgrading of Spirulina platensis residue oil using silica alumina catalyst,†Int. J. Renew. Energy Res., 9, (4), pp. 1733–1740, 2019.

D. R. Wicakso, Sutijan, Rochmadi, & A. Budiman, “Study of catalytic upgrading of biomass tars using Indonesian iron ore,†in AIP Conference Proceedings, Mar. 2017, 1823, (1), p. 020094, doi: 10.1063/1.4978167.

Y. S. Pradana, M. Hartono, & A. Prasetya, “Evaluation of household pyrolitic stove performance: Effect of bottom air apertures,†Int. J. Adv. Sci. Eng. Inf. Technol., 8, (5), pp. 2005–2011, 2018, doi: 10.18517/ijaseit.8.5.3810.

S. Wan, N. Zheng, J. Zhang, & J. Wang, “Role of neutral extractives and inherent active minerals in pyrolysis of agricultural crop residues and bio-oil formations,†Biomass and Bioenergy, 122, (January), pp. 53–62, 2019, doi: 10.1016/j.biombioe.2019.01.010.

H. Weldekidan et al., “Distribution of solar pyrolysis products and product gas composition produced from agricultural residues and animal wastes at different operating parameters,†Renew. Energy, 151, pp. 1102–1109, 2020, doi: 10.1016/j.renene.2019.11.107.

H. Sudibyo, Y. S. Pradana, A. Budiman, & W. Budhijanto, “Municipal Solid Waste Management in Indonesia - A Study about Selection of Proper Solid Waste Reduction Method in D.I. Yogyakarta Province,†Energy Procedia, 143, pp. 494–499, 2017, doi: 10.1016/j.egypro.2017.12.716.

Y. S. Pradana, W. Masruri, F. A. Azmi, E. A. Suyono, H. Sudibyo, & Rochmadi, “Extractive-transesterification of Microalgae Arthrospira sp. Using Methanol-Hexane Mixture as solvent,†Int. J. Renew. Energy Res., 8, (3), pp. 1499–1507, 2018.

Y. S. Pradana & A. Prasetya, “Performance evaluation of household pyrolytic stove: Effect of outer air holes condition,†AIP Conf. Proc., 1823, 2017, doi: 10.1063/1.4978142.

J. Zhang, J. Liu, L. Kou, X. Zhang, & T. Tan, “Bioethanol production from cellulose obtained from the catalytic hydro-deoxygenation (lignin-first refined to aviation fuel) of apple wood,†Fuel, 250, (March), pp. 245–253, 2019, doi: 10.1016/j.fuel.2019.03.020.

L. Y. Vega, L. López, C. F. Valdés, & F. Chejne, “Assessment of energy potential of wood industry wastes through thermochemical conversions,†Waste Manag., 87, pp. 108–118, 2019, doi: 10.1016/j.wasman.2019.01.048.

Y. S. Pradana, Daniyanto, M. Hartono, L. Prasakti, & A. Budiman, “Effect of calcium and magnesium catalyst on pyrolysis kinetic of Indonesian sugarcane bagasse for biofuel production,†Energy Procedia, 158, pp. 431–439, 2019, doi: 10.1016/j.egypro.2019.01.128.

T. Yuan, W. He, G. Yin, & S. Xu, “Comparison of bio-chars formation derived from fast and slow pyrolysis of walnut shell,†Fuel, 261, (August 2019), p. 116450, 2020, doi: 10.1016/j.fuel.2019.116450.

Q. Wang, K. Han, J. Gao, H. Li, & C. Lu, “The pyrolysis of biomass briquettes: Effect of pyrolysis temperature and phosphorus additives on the quality and combustion of bio-char briquettes,†Fuel, 199, pp. 488–496, 2017, doi: 10.1016/j.fuel.2017.03.011.

X. Wang et al., “Biomass derived N-doped biochar as efficient catalyst supports for CO2 methanation,†J. CO2 Util., 34, (September), pp. 733–741, 2019, doi: 10.1016/j.jcou.2019.09.003.

M. P. Remacha, S. Jiménez, & J. Ballester, “Devolatilization of millimeter-sized biomass particles at high temperatures and heating rates. Part 2: Modeling and validation for thermally-thin and -thick regimes,†Fuel, 234, (June), pp. 707–722, 2018, doi: 10.1016/j.fuel.2018.07.017.

A. Soria-Verdugo et al., “Comparison of wood pyrolysis kinetic data derived from thermogravimetric experiments by model-fitting and model-free methods,†Energy Convers. Manag., 212, (January), p. 112818, 2020, doi: 10.1016/j.enconman.2020.112818.

R. K. Mishra & K. Mohanty, “Pyrolysis kinetics and thermal behavior of waste sawdust biomass using thermogravimetric analysis,†Bioresour. Technol., 251, (October 2017), pp. 63–74, 2018, doi: 10.1016/j.biortech.2017.12.029.

T. Xu, F. Xu, Z. Hu, Z. Chen, & B. Xiao, “Non-isothermal kinetics of biomass-pyrolysis-derived-tar (BPDT) thermal decomposition via thermogravimetric analysis,†Energy Convers. Manag., 138, pp. 452–460, 2017, doi: 10.1016/j.enconman.2017.02.013.

V. Dhyani, J. Kumar, & T. Bhaskar, “Thermal decomposition kinetics of sorghum straw via thermogravimetric analysis,†Bioresour. Technol., 245, (August), pp. 1122–1129, 2017, doi: 10.1016/j.biortech.2017.08.189.

S. Sobek & S. Werle, “Kinetic modelling of waste wood devolatilization during pyrolysis based on thermogravimetric data and solar pyrolysis reactor performance,†Fuel, 261, (August 2019), p. 116459, 2020, doi: 10.1016/j.fuel.2019.116459.

A. M. Widiyannita, R. B. Cahyono, A. Budiman, Sutijan, & T. Akiyama, “Study of pyrolysis of ulin wood residues,†AIP Conf. Proc., 1755, 2016, doi: 10.1063/1.4958487.

H. E. Kissinger, “Variation of peak temperature with heating rate in differential thermal analysis,†J. Res. Natl. Bur. Stand. (1934)., 57, (4), p. 217, 1956, doi: 10.6028/jres.057.026.

T. Ozawa, “A New Method of Analyzing Thermogravimetric Data,†Bull. Chem. Soc. Jpn., 38, (11), pp. 1881–1886, 1965, doi: 10.1246/bcsj.38.1881.

J. H. Flynn & L. A. Wall, “A quick, direct method for the determination of activation energy from thermogravimetric data,†J. Polym. Sci. Part B Polym. Lett., 4, (5), pp. 323–328, May 1966, doi: 10.1002/pol.1966.110040504.

R. L. Blaine & H. E. Kissinger, “Homer Kissinger and the Kissinger equation,†Thermochim. Acta, 540, pp. 1–6, 2012, doi: 10.1016/j.tca.2012.04.008.

A. Khawam, “Application of solid-state kinetics to desolvation reactions,†University of Iowa, 2007.

M. Poletto, “Thermogravimetric Analysis and Kinetic Study of Pine Wood Pyrolysis,†Rev. Ciência da Madeira - RCM, 7, (2), pp. 111–118, 2016, doi: 10.12953/2177-6830/rcm.v7n2p111-118.

J. Ge, R. Q. Wang, & L. Liu, “Study on the Thermal Degradation Kinetics of the Common Wooden Boards,†Procedia Eng., 135, pp. 72–82, 2016, doi: 10.1016/j.proeng.2016.01.082.

A. S. Khan et al., “Kinetics and thermodynamic parameters of ionic liquid pretreated rubber wood biomass,†J. Mol. Liq., 223, pp. 754–762, 2016, doi: 10.1016/j.molliq.2016.09.012.




DOI: http://dx.doi.org/10.18517/ijaseit.10.4.3640

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