Electrochemical Sensor Based on Molecularly Imprinted Polymer (MIP) for Simazine Pesticide Detection

Yohandri Bow, Adi Syakdani, Indah Purnamasari, - Rusdianasari

Abstract


The use of pesticides and herbicides containing the active ingredient simazine must be carried out strictly so as not to cause adverse effects on humans and the environment. Measurement of contaminants in the form of simazine as one of the active ingredients of pesticides and herbicides is very important. An imprinted polymer molecule (MIP) has been made using methacrylic acid (MAA) as a functional monomer and ethylene glycol dimethyl acrylate (EGDMA) as a cross-linker. This research resulted in a molecularly imprinted membrane for the specific recognition of simazine. The electrochemical potential used with MIP coated electrodes provides both qualitative and quantitative detection of simazine. Polymer coated molecular-based potentiometric sensors (MIP) are promising analytical tools for developing highly selective analytical sensors. Optimal conditions for the production of simazine MIP were found to be 6.02 mL of chloroform, 0.025 g of simazine, 0.9 mL of MAA, 1.57 mL of EGDMA, and 0.07 g of benzoyl peroxide (BPO) with a heating time of 150 minutes at 70oC. The results of the electrode performance test resulted in stable and unstable conditions, with a measurement range on the surface of the double-layer electrode with a coefficient distribution of 0.9897. Compared with electrochemical procedures with MIPs sensors and spectrophotometry, it produces a significant value with a 95% confidence level with Q-test results for the 0.48 ppm level with spectrometric procedures obtained Q exp = 0.25, Q crit value is 0.71.

Keywords


Simazine pesticide; molecularly imprinted polymer; electrochemical sensor.

Full Text:

PDF

References


Y. Saylan, S. Akgönüllü, H. Yavuz, S. Ünal, and A. Denizli, “Molecularly imprinted polymer based sensors for medical applications,†Sensors (Switzerland), vol. 19, no. 6, 2019, doi: 10.3390/s19061279.

M. Pesavento, S. Marchetti, L. De Maria, L. Zeni, and N. Cennamo, “Sensing by molecularly imprinted polymer: Evaluation of the binding properties with different techniques,†Sensors (Switzerland), vol. 19, no. 6, pp. 1–18, 2019, doi: 10.3390/s19061344.

U. Latif, L. Ping, and F. L. Dickert, “Conductometric sensor for pah detection with molecularly imprinted polymer as recognition layer,†Sensors (Switzerland), vol. 18, no. 3, 2018, doi: 10.3390/s18030767.

L. Xu, Y. A. Huang, Q. J. Zhu, and C. Ye, “Chitosan in molecularly-imprinted polymers: Current and future prospects,†Int. J. Mol. Sci., vol. 16, no. 8, pp. 18328–18347, 2015, doi: 10.3390/ijms160818328.

T. Wirawan, G. Supriyanto, and A. Soegianto, “Preparation of a new Cd(II)-imprinted polymer and its application to preconcentration and determination of cd(ii) ion from aqueous solution by SPE-FAAS,†Indones. J. Chem., vol. 19, no. 1, pp. 97–105, 2019, doi: 10.22146/ijc.27703.

Rusdianasari, A. Syakdani, Y. Bow, T. Dewi, A. J. far Shodiq, and S. Arita, “Combination of electrocogulation and aeration processes by addition nacl for leachate treatment,†Int. J. Adv. Sci. Eng. Inf. Technol., vol. 10, no. 1, pp. 400–406, 2020, doi: 10.18517/ijaseit.10.1.11012.

Rusdianasari, A. Taqwa, Jaksen, and A. Syakdani, “Treatment optimization of electrocoagulation (EC) in purifying palm oil mill effluents (POMEs),†J. Eng. Technol. Sci., vol. 49, no. 5, pp. 604–617, 2017, doi: 10.5614/j.eng.technol.sci.2017.49.5.4.

E. Spieker and P. A. Lieberzeit, “Molecular Imprinting Studies for Developing QCM-sensors for Bacillus Cereus,†Procedia Eng., vol. 168, pp. 561–564, 2016, doi: 10.1016/j.proeng.2016.11.525.

Rusdianasari, A. Taqwa, Jaksen, and A. Syakdani, “Treatment of landfill leachate by electrocoagulation using aluminum electrodes,†MATEC Web Conf., vol. 101, 2017, doi: 10.1051/matecconf/201710102010.

Y. Bow, E. Sutriyono, S. Nasir, and I. Iskandar, “Preparation of molecularly imprinted polymers simazine as material potentiometric sensor,†MATEC Web Conf., vol. 101, pp. 8–12, 2017, doi: 10.1051/matecconf/201710101002.

Y. Bow, E. Sutriyono, S. Nasir, and I. Iskandar, “Molecularly Imprinted Polymers (MIP) based electrochemical sensors for detection of endosulfan pesticide,†Int. J. Adv. Sci. Eng. Inf. Technol., vol. 7, no. 2, pp. 662–668, 2017, doi: 10.18517/ijaseit.7.2.1064.

S. Nishitani and T. Sakata, “Potentiometric Adsorption Isotherm Analysis of a Molecularly Imprinted Polymer Interface for Small-Biomolecule Recognition,†ACS Omega, vol. 3, no. 5, pp. 5382–5389, 2018, doi: 10.1021/acsomega.8b00627.

M. M. Moein, A. Abdel-Rehim, and M. Abdel-Rehim, “Recent applications of molecularly imprinted sol-gel methodology in sample preparation,†Molecules, vol. 24, no. 16, pp. 1–12, 2019, doi: 10.3390/molecules24162889.

A. Meidinariasty, Rusdianasari, Y. Bow, I. Rusnadi, and A. Lutfi Fuadi, “Treatment of Leachate from Garbage using Electrocoagulation Type MP-P (MonoPolar-Paralel) Methode,†J. Phys. Conf. Ser., vol. 1167, no. 1, 2019, doi: 10.1088/1742-6596/1167/1/012054.

G. Liu et al., “Recent advances and perspectives of molecularly imprinted polymer-based fluorescent sensors in food and environment analysis,†Nanomaterials, vol. 9, no. 7, 2019, doi: 10.3390/nano9071030.

M. E. Khalifa and A. B. Abdallah, “Molecular imprinted polymer based sensor for recognition and determination of profenofos organophosphorous insecticide,†Biosens. Bioelectron. X, vol. 2, no. August, p. 100027, 2019, doi: 10.1016/j.biosx.2019.100027.

P. S. Sharma, A. Garcia-Cruz, M. Cieplak, K. R. Noworyta, and W. Kutner, “‘Gate effect’ in molecularly imprinted polymers: the current state of understanding,†Curr. Opin. Electrochem., vol. 16, pp. 50–56, 2019, doi: 10.1016/j.coelec.2019.04.020.

D. Zembrzuska et al., “Electrochemically initiated co-polymerization of monomers of different oxidation potentials for molecular imprinting of electroactive analyte,†Sensors Actuators, B Chem., vol. 298, no. July 2019, p. 126884, 2019, doi: 10.1016/j.snb.2019.126884.

Z. Guo et al., “Molecularly imprinted polymer/metal organic framework based chemical sensors,†Coatings, vol. 6, no. 4, 2016, doi: 10.3342/coatings6040042.

Y. Bow, Hairul, and I. Hajar, “Molecularly imprinted polymer (MIP) based PVC-membrane-coated graphite electrode for the determination of heavy metals,†Int. J. Adv. Sci. Eng. Inf. Technol., vol. 5, no. 6, pp. 422–425, 2015, doi: 10.18517/ijaseit.5.6.594.

W. A. El-Said, M. Abdelshakour, J. H. Choi, and J. W. Choi, “Application of conducting polymer nanostructures to electrochemical biosensors,†Molecules, vol. 25, no. 2, pp. 1–11, 2020, doi: 10.3390/molecules25020307.

S. A. Rezvani Ivari, A. Darroudi, M. H. Arbab Zavar, G. Zohuri, and N. Ashraf, “Ion imprinted polymer based potentiometric sensor for the trace determination of Cadmium (II) ions,†Arab. J. Chem., vol. 10, pp. S864–S869, 2017, doi: 10.1016/j.arabjc.2012.12.021.

F. Yanto, I. Royani, and Suheryanto, “Application of nano electrode Ag/AgCl on potentiometric sensor based on molecularly imprinted polymer (MIP) to verify caffeine,†J. Phys. Conf. Ser., vol. 1751, no. 1, pp. 0–7, 2021, doi: 10.1088/1742-6596/1751/1/012074.

Novarini, Rusdianasari, S Kurniawan, Y Bow, “Waste-to-Energy (WTE) Method to Mitigate Harmful Environmental and Health Consequences Due to LDPE Plastic Waste,†IOP Conference Series: Earth and Environmental Science 810 (1), 012014, 2021, doi:10.1088/1755-1315/810/1/012014

B. Uka, J. Kieninger, G.A. Urban, A. Weltin, “Electrochemical microsensor for microfluidic glyphosate monitoring in water using MIP-based concentrators,†ACS Sensors, Vol. 6(7), pp. 2738-2746, doi: https://doi.org/10.1021/acssensors.1c00884

S. Rahman, B. Bozal-Palabiyik, D.N. Unal… “Molecularly imprinted polymers (MIPs) combined with nanomaterials as electrochemical sensing applications for environmental pollutants,†Trends in Environmental Analytical Chemistry, Vol. 36, doi: https://doi.org/10.1016/j.teac.2022.e00176.




DOI: http://dx.doi.org/10.18517/ijaseit.13.1.16688

Refbacks

  • There are currently no refbacks.


Published by INSIGHT - Indonesian Society for Knowledge and Human Development