Full Factorial Design Analysis and Characterization of Polyethylene, Starch and Aloe Vera Gel Thin Film Formulation

Siti Fatma Abd Karim, Junaidah Jai, Ku Halim Ku Hamid, Mohd Hariz Mior Muzamin, Nadia Kamarrudin, Rabiatul Adawiyah Abdol Aziz

Abstract


The polyethylene-thermoplastic (PE/TPS) based film was introduced many years ago, but the compatibility of PE/TPS still an issue because synthetic compatibilizer has a safety drawback. In this work, aloe vera (AV) was introduced as a compatibilizer to enhance stress and characteristics of PE/TPS film. This paper determines the optimum PE/TPS/AV film formulation using full factorial design (FFD) analysis. Melt blending and hot-press techniques were used to prepare the film. Four selected PE/TPS/AV samples were chosen to discuss mechanical properties, functional groups, thermal degradation, and thermal properties changes. Based on FFD, PE was the most significant material that caused substantial changes in the film's mechanical properties. Concurrently, the interaction between PE/TPS and TPS/AV significantly influenced the value of the secant modulus. The addition of AV into TPS improved the stress and reduced the strain. New peaks are present in TPS/AV that share the same functional group with PE. Thus, improving the stress of the film. The presence of AV caused peaks 2916 cm-1 and 2849 cm-1 of TPS to strengthen at once; the thermal degradation increases tremendously from 282 °C to 354.70 °C. The melting temperature showed a reduction when TPS/AV was added into PE, but the crystallization temperature did not significantly change. However, significant changes occurred for crystallization enthalpy when TPS/AV was incorporated in PE at once, affecting the degree of crystallinity. In conclusion, AV was suggested to act as a compatibilizer/crosslinker or plasticizer to improve PE film packaging properties.

Keywords


Full factorial design; design expert; thin film; polyethylene-starch film; Aloe vera gel.

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References


D. Datta and G. Halder, “Effect of media on degradability, physico-mechanical and optical properties of synthesized polyolefinic and PLA film in comparison with casted potato/corn starch biofilm,” Process Saf. Environ. Prot., vol. 124, pp. 39–62, 2019.

M. Ahmadi, T. Behzad, R. Bagheri, and P. Heidarian, “Effect of cellulose nanofibers and acetylated cellulose nanofibers on the properties of low-density polyethylene/thermoplastic starch blends,” Polym. Int., vol. 67, no. 8, pp. 993–1002, 2018.

T. Mazerolles, M. C. Heuzey, M. Soliman, H. Martens, R. Kleppinger, and M. A. Huneault, “Development of multilayer barrier films of thermoplastic starch and low-density polyethylene,” J. Polym. Res., vol. 27, no. 2, pp. 1–15, 2020.

Y. Hammache, A. Serier, and S. Chaoui, “The effect of thermoplastic starch on the properties of polypropylene/high density polyethylene blend reinforced by nano-clay,” Mater. Res. Express, vol. 7, no. 2, pp. 1–13, 2020.

T. Mazerolles, M. C. Heuzey, M. Soliman, H. Martens, R. Kleppinger, and M. A. Huneault, “Development of co-continuous morphology in blends of thermoplastic starch and low-density polyethylene,” Carbohydr. Polym., vol. 206, no. June 2018, pp. 757–766, 2019.

R. Mani et al., “Biodegradability study by FTIR and DSC of polymers films based on polypropylene and Cassava starch,” Orbital, vol. 11, no. 8, pp. 71–82, Apr. 2019.

N. Khanoonkon, R. Yoksan, and A. A. Ogale, “Morphological characteristics of stearic acid-grafted starch-compatibilized linear low density polyethylene/thermoplastic starch blown film,” Eur. Polym. J., vol. 76, pp. 266–277, 2016.

J. Aburto et al., “Properties of octanoated starch and its blends with polyethylene,” Carbohydr. Polym., vol. 34, no. 1–2, pp. 101–112, 1997.

A. Kaboorani, N. Gray, Y. Hamzeh, and A. Abdulkhani, “Tailoring the low-density polyethylene - thermoplastic starch composites using cellulose nanocrystals and compatibilizer,” Polym. Test., vol. 93, p. 107007, 2021.

A. A. O. Nattaporn Khanoonkona, Rangrong Yoksana, “Effect of stearic acid-grafted starch compatibilizer on properties oflinear low density polyethylene/thermoplastic starch blown film,” Carbohydr. Polym., vol. 137, pp. 165–173, 2016.

D. Datta and G. Halder, “Enhancing degradability of plastic waste by dispersing starch into low density polyethylene matrix,” Process Saf. Environ. Prot., vol. 114, pp. 143–152, 2018.

M. Sabetzadeh, R. Bagheri, and M. Masoomi, “Morphology and rheological properties of compatibilized low-density polyethylene/linear low-density polyethylene/thermoplastic starch blends,” J. Appl. Polym. Sci., vol. 134, no. 16, pp. 1–9, 2017.

D. M. Nguyen, T. V. V. Do, A. C. Grillet, H. Ha Thuc, and C. N. Ha Thuc, “Biodegradability of polymer film based on low density polyethylene and cassava starch,” Int. Biodeterior. Biodegrad., vol. 115, pp. 257–265, 2016.

T. Panrong, T. Karbowiak, and N. Harnkarnsujarit, “Effects of acetylated and octenyl-succinated starch on properties and release of green tea compounded starch/LLDPE blend films,” J. Food Eng., vol. 284, p. 110057, 2020.

R. Thipmanee, S. Lukubira, A. A. Ogale, and A. Sane, “Enhancing distributive mixing of immiscible polyethylene/thermoplastic starch blend through zeolite ZSM-5 compounding sequence,” Carbohydr. Polym., vol. 136, pp. 812–819, 2015.

T. Panrong, T. Karbowiak, and N. Harnkarnsujarit, “Thermoplastic starch and green tea blends with LLDPE films for active packaging of meat and oil-based products,” Food Packag. Shelf Life, vol. 21, p. 100331, 2019.

N. Amigo et al., “Effect of starch nanoparticles on the crystallization kinetics and photodegradation of high density polyethylene,” Compos. Part B Eng., vol. 174, p. 106979, 2019.

N. Gray, Y. Hamzeh, A. Kaboorani, and A. Abdulkhani, “Influence of cellulose nanocrystal on strength and properties of low density polyethylene and thermoplastic starch composites,” Ind. Crops Prod., vol. 115, pp. 298–305, 2018.

A. B. Martins, A. K. Cattelan, and R. M. C. Santana, “How the compatibility between polyethylene and thermoplastic starch can be improved by adding organic acids?,” Polym. Bull., vol. 75, no. 5, pp. 2197–2212, 2018.

R. Radfar et al., “Optimization of antibacterial and mechanical properties of an active LDPE/starch/nanoclay nanocomposite film incorporated with date palm seed extract using D-optimal mixture design approach,” Int. J. Biol. Macromol., vol. 158, pp. 790–799, 2020.

T. J. Gutiérrez and G. González, “Effect of Cross-Linking with Aloe vera Gel on Surface and Physicochemical Properties of Edible Films Made from Plantain Flour,” Food Biophys., vol. 12, no. 1, pp. 11–22, 2017.

S. R. Kanatt and S. H. Makwana, “Development of active, water-resistant carboxymethyl cellulose-poly vinyl alcohol-Aloe vera packaging film,” Carbohydr. Polym., vol. 227, p. 115303, 2020.

G. F. El Fawal, A. M. Omer, and T. M. Tamer, “Evaluation of antimicrobial and antioxidant activities for cellulose acetate films incorporated with Rosemary and Aloe Vera essential oils,” J. Food Sci. Technol., vol. 56, no. 3, pp. 1510–1518, 2019.

T. J. Gutiérrez and K. Álvarez, “Physico-chemical properties and in vitro digestibility of edible films made from plantain flour with added Aloe vera gel,” J. Funct. Foods, vol. 26, pp. 750–762, 2016.

R. Ortega-Toro, S. Collazo-Bigliardi, J. Roselló, P. Santamarina, and A. Chiralt, “Antifungal starch-based edible films containing Aloe vera,” Food Hydrocoll., vol. 72, pp. 1–10, 2017.

L. Yesappa et al., “Investigation of the Structure, Optical and Electrical Properties of Lithium Perchlorate Doped Polyaniline Composite: Aloe Vera Used as a Bio-Plasticizer,” J. Electron. Mater., vol. 46, no. 12, pp. 6965–6976, 2017.

M. I. Pinzon, L. T. Sanchez, O. R. Garcia, R. Gutierrez, J. C. Luna, and C. C. Villa, “Increasing shelf life of strawberries (Fragaria ssp) by using a banana starch-chitosan-Aloe vera gel composite edible coating,” Int. J. Food Sci. Technol., vol. 55, no. 1, pp. 92–98, 2019.

M. I. Pinzon, O. R. Garcia, and C. C. Villa, “The influence of Aloe vera gel incorporation on the physicochemical and mechanical properties of banana starch-chitosan edible films,” J. Sci. Food Agric., vol. 98, no. 11, pp. 4042–4049, 2018.

U. Verma, R. Rajput, and J. B. Naik, “Development and characterization of Fast Dissolving Film of Chitosan embedded Famotidine Using 32 Full Factorial Design Approach,” Mater. Today Proc., vol. 5, no. 1, pp. 408–414, 2018.

P. R. Vuddanda, M. Montenegro-Nicolini, J. O. Morales, and S. Velaga, “Effect of plasticizers on the physico-mechanical properties of pullulan based pharmaceutical oral films,” Eur. J. Pharm. Sci., vol. 96, pp. 290–298, 2017.

X. Chen, L. Zhou, X. Pan, J. Hu, Y. Hu, and S. Wei, “Effect of different compatibilizers on the mechanical and thermal properties of starch/polypropylene blends,” J. Appl. Polym. Sci., vol. 133, no. 17, pp. 1–7, 2016.

M. Karimi and D. Biria, “The promiscuous activity of alpha-amylase in biodegradation of low-density polyethylene in a polymer-starch blend,” Sci. Rep., vol. 9, no. 1, pp. 1–10, 2019.

S. F. Abd Karim, J. B. Jai, K. H. Ku Hamid, and A. W. Abdul Jalil, “Characteristics and mechanical properties changes due to incorporation of aloe vera in polyethylene-based film,” Sci. Res. J., vol. 17, no. 2, pp. 61–80, 2020.

D. Datta and G. Halder, “Blending of phthalated starch and surface functionalized rice husk extracted nanosilica with LDPE towards developing an efficient packaging substitute,” Environ. Sci. Pollut. Res., vol. 27, no. 2, pp. 1533–1557, 2020.

M. Sabetzadeh, R. Bagheri, and M. Masoomi, “Effect of Oxidized Starch on Morphology, Rheological and Tensile Properties of Low-Density Polyethylene/Linear Low-Density Polyethylene/Thermoplastic Oxidized Starch Blends,” J. Polym. Environ., vol. 26, no. 6, pp. 2219–2226, 2018.

R. Minjares-Fuentes, A. Femenia, F. Comas-Serra, and V. M. Rodríguez-González, “Compositional and structural features of the main bioactive polysaccharides present in the aloe vera plant,” J. AOAC Int., vol. 101, no. 6, pp. 1711–1719, 2018.

L. Wang et al., “Effects of fatty acid chain length on properties of potato starch–fatty acid complexes under partially gelatinization,” Int. J. Food Prop., vol. 21, no. 1, pp. 2121–2134, 2018.

S. Fatma, A. Karim, J. Jai, K. Halim, K. Hamid, and A. Wafi, “Effect of crude palm oil , Aloe vera , glycerol , and starch on characteristics and mechanical properties of polyethylene film,” Malaysian J. Chem. Eng. Technol., vol. 3, no. 1, pp. 16–24, 2020.

L. Panahi, M. Gholizadeh, and R. Hajimohammadi, “Investigating the degradability of polyethylene using starch, oxo-material, and polylactic acid under the different environmental conditions,” Asia-Pacific J. Chem. Eng., vol. 15, no. 1, pp. 1–12, 2020.

O. ard Saibuatong and M. Phisalaphong, “Novo aloe vera-bacterial cellulose composite film from biosynthesis,” Carbohydr. Polym., vol. 79, pp. 455–460, 2010.

A. Ramírez-Hernández et al., “Thermal, morphological and structural characterization of a copolymer of starch and polyethylene,” Carbohydr. Res., vol. 488, p. 107907, 2020.

M. P. Ong-ard Saibuatong, “Novo aloe vera–bacterial cellulose composite film from biosynthesis,” Carbohydr. Polym., vol. 79, pp. 455–460, 2010.

C. Agudelo-Cuartas, D. Granda-Restrepo, P. J. A. Sobral, and W. Castro, “Determination of mechanical properties of whey protein films during accelerated aging: Application of FTIR profiles and chemometric tools,” J. Food Process Eng., vol. 44, no. 5, p. e13477, 2020.

L. Q. Khor and K. Y. Cheong, “Aloe vera gel as natural organic dielectric in electronic application,” J. Mater. Sci. Mater. Electron., vol. 24, no. 7, pp. 2646–2652, 2013.

S. S. and G. H. Datta, Deepshikha, “Effect of thickness and starch phthalate/starch content on the degradability of LDPE/silane-modified nanosilica films: a comparative parametric optimization,” Polym. Bull., vol. 78, pp. 2287–2328, 2021.

X. Liu et al., “Thermal degradation and stability of starch under different processing conditions,” Starch/Starke, vol. 65, pp. 48–60, 2013.

J. Chen, X. Wang, Z. Long, S. Wang, J. Zhang, and L. Wang, “Preparation and performance of thermoplastic starch and microcrystalline cellulose for packaging composites: Extrusion and hot pressing,” Int. J. Biol. Macromol., vol. 165, pp. 2295–2302, 2020.

N. Nordin, S. H. Othman, S. A. Rashid, and R. K. Basha, “Effects of glycerol and thymol on physical, mechanical, and thermal properties of corn starch films,” Food Hydrocoll., vol. 106, p. 105884, 2020.

L. Nieto-Suaza, L. Acevedo-Guevara, L. T. Sánchez, M. I. Pinzón, and C. C. Villa, “Characterization of Aloe vera-banana starch composite films reinforced with curcumin-loaded starch nanoparticles,” Food Struct., vol. 22, p. 100131, 2019.

C. I. Nindo, J. R. Powers, and J. Tang, “Thermal Properties of Aloe Vera Powder and Rheology of Reconstituted Gels,” Trans. ASABE, vol. 53, no. 4, pp. 1193–1200, 2010.

E. Stasi et al., “Biodegradable carbon-based ashes/maize starch composite films for agricultural applications,” Polymers (Basel)., vol. 12, no. 3, pp. 1–16, 2020.

D. Li, L. Zhou, X. Wang, L. He, and X. Yang, “Effect of Crystallinity of Polyethylene with Different Densities on Breakdown Strength and Conductance Property,” Materials (Basel)., vol. 12, no. 11, p. 1746, 2019.

A. L. Da Róz, M. D. Zambon, A. A. S. Curvelo, and A. J. F. Carvalho, “Thermoplastic starch modified during melt processing with organic acids: The effect of molar mass on thermal and mechanical properties,” Ind. Crops Prod., vol. 33, no. 1, pp. 152–157, 2011.




DOI: http://dx.doi.org/10.18517/ijaseit.11.6.15343

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